You would look up Italian copyright law, only to discover that it has only existed since 1941 and that the rights of authors (i.e., painters) last for 70 years after their death. Find out when LdV died, add 70 years and see if there is any copyright on ANY of his works.
Since the 1880s, Italian copyright was administered by Società Italiana degli Autori ed Editori
(Italian Society of Authors and Publishers) - S.I.A.E., which became a quasi-government commission in the 1930s.
Under USA law, nothing published prior to 1923 has any copyright. 17 USC 301.